All-time best penalty takers
| # | Name | Matches | 11m | |
|---|---|---|---|---|
| 1 |  | Borja Bastón | 119 | 14 |
| 2 |  | Susaeta | 154 | 11 |
| 3 |  | Carlos | 257 | 10 |
| 4 |  | Antón | 249 | 7 |
| 5 |  | José Sánchez Lage | 118 | 6 |
| 6 |  | Diego Cervero | 74 | 5 |
 | Peter Dubovský | 129 | 5 | |
 | Emilín García | 224 | 5 | |
 | Geni | 92 | 5 | |
| 10 |  | Bango | 170 | 4 |
 | Julio Dely Valdés | 105 | 4 | |
 | Isidro Lángara | 90 | 4 | |
 | Ortuño | 38 | 4 | |
 | Tensi | 97 | 4 | |
 | Toché | 139 | 4 | |
| 16 |  | Thomas Christiansen | 55 | 3 |
 | Linares | 138 | 3 | |
 | Oli | 233 | 3 | |
 | Santi Cazorla | 89 | 3 | |
 | Sergio Tejera | 103 | 3 | |
| 21 |  | Santiago Colombatto | 120 | 2 |
 | Janko Janković | 169 | 2 | |
 | Slaviša Jokanović | 69 | 2 | |
 | José María | 108 | 2 | |
 | Luisin | 28 | 2 | |
 | Roberto Pompei | 99 | 2 | |
 | Robert Prosinečki | 32 | 2 | |
 | Đorđe Tomić | 64 | 2 | |
 | Federico Viñas | 53 | 2 | |
| 30 |  | Aarón | 45 | 1 |
 | Florencio Amarilla | 33 | 1 | |
 | Artabe | 50 | 1 | |
 | Josip Brekalo | 15 | 1 | |
 | José De La Torre | 32 | 1 | |
 | Engonga | 12 | 1 | |
 | Galán | 90 | 1 | |
 | Juan González | 70 | 1 | |
 | Gorriarán | 212 | 1 | |
 | Herrerita | 212 | 1 | |
 | Iñigo Idiakez | 34 | 1 | |
 | Iván Ania | 175 | 1 | |
 | Jorge Pombo | 24 | 1 | |
 | Joselu | 46 | 1 | |
 | Koba Koindredi | 20 | 1 | |
 | Manu Vallejo | 16 | 1 | |
 | Peter Møller | 45 | 1 | |
 | Viktor Onopko | 221 | 1 | |
 | Óscar Pérez | 15 | 1 | |
 | Paulino de la Fuente | 65 | 1 | |
 | Paulo Bento | 144 | 1 | |
 | Rodri | 39 | 1 | |
 | Pedro Sara | 52 | 1 | |
 | Saúl Berjón | 114 | 1 | |
 | Toni Cuervo | 189 | 1 |