All-time best penalty takers
| # | Name | Matches | 11m | |
|---|---|---|---|---|
| 1 |  | Hierro | 89 | 10 |
| 2 |  | David Villa | 98 | 8 |
 | Míchel | 66 | 8 | |
 | Sergio Ramos | 180 | 8 | |
| 5 |  | Xabi Alonso | 114 | 6 |
| 6 |  | Fernando Torres | 110 | 5 |
| 7 |  | Dani | 25 | 4 |
 | Mikel Oyarzabal | 64 | 4 | |
| 9 |  | Butragueño | 69 | 3 |
 | Pep Guardiola | 47 | 3 | |
 | Pirri | 41 | 3 | |
 | Piru Gaínza | 33 | 3 | |
 | Raúl | 102 | 3 | |
 | Zaldúa | 5 | 3 | |
| 15 |  | Álvaro Morata | 87 | 2 |
 | Carrasco | 33 | 2 | |
 | César Rodríguez | 12 | 2 | |
 | David Silva | 125 | 2 | |
 | Goikoetxea | 39 | 2 | |
 | Juanito | 34 | 2 | |
 | László Kubala | 19 | 2 | |
 | Mendieta | 40 | 2 | |
 | Rodri | 74 | 2 | |
 | Señor | 41 | 2 | |
| 25 |  | Álex Baena | 29 | 1 |
 | Arrate | 6 | 1 | |
 | Begiristáin | 22 | 1 | |
 | Bienzobas | 2 | 1 | |
 | Bryan Zaragoza | 3 | 1 | |
 | Campos | 6 | 1 | |
 | Claramunt | 23 | 1 | |
 | Donato | 12 | 1 | |
 | Enrique Collar | 16 | 1 | |
 | Ferran Torres | 67 | 1 | |
 | Guerrero | 41 | 1 | |
 | Iniesta | 131 | 1 | |
 | Iraragorri | 8 | 1 | |
 | Isidro Lángara | 12 | 1 | |
 | Juan Mata | 41 | 1 | |
 | Lamine Yamal | 37 | 1 | |
 | López Ufarte | 15 | 1 | |
 | Manolo | 28 | 1 | |
 | Megido | 1 | 1 | |
 | Pablo Sarabia | 27 | 1 | |
 | Quesada | 9 | 1 | |
 | Quini | 35 | 1 | |
 | Santi Cazorla | 81 | 1 | |
 | Satrústegui | 32 | 1 | |
 | Toni Muñoz | 10 | 1 | |
 | Vicente | 38 | 1 |