All-time best penalty takers
| # | Name | Matches | 11m | |
|---|---|---|---|---|
| 1 |  | Óscar Trejo | 333 | 16 |
| 2 |  | Isi Palazón | 275 | 8 |
| 3 |  | Piti | 198 | 7 |
 | Raúl de Tomás | 116 | 7 | |
| 5 |  | Adrián Embarba | 235 | 6 |
 | Luis Cembranos | 119 | 6 | |
 | Mario Suárez | 110 | 6 | |
 | Fernando Morena | 34 | 6 | |
| 9 |  | Julio Álvarez | 26 | 5 |
 | Peragón | 115 | 5 | |
 | Hugo Sánchez | 30 | 5 | |
| 12 |  | Aganzo | 74 | 4 |
 | Emiliano Armenteros | 61 | 4 | |
| 14 |  | Radamel Falcao | 80 | 3 |
 | Jonathan Viera | 28 | 3 | |
 | Juanito | 31 | 3 | |
 | Joaquín Larrivey | 37 | 3 | |
 | Pablo Sanz | 126 | 3 | |
 | Toni Polster | 31 | 3 | |
 | Tanco | 99 | 3 | |
 | Trashorras | 219 | 3 | |
| 22 |  | Stjepan Andrijašević | 51 | 2 |
 | Daniel Aquino | 44 | 2 | |
 | Baroja | 42 | 2 | |
 | Bolo | 195 | 2 | |
 | Alberto Bueno | 77 | 2 | |
 | Diego Costa | 16 | 2 | |
 | Alejandro Domínguez | 53 | 2 | |
 | Patrick Ebert | 38 | 2 | |
 | Javi Guerra | 93 | 2 | |
 | Diego Klimowicz | 44 | 2 | |
 | Llorens | 69 | 2 | |
 | Míchel Sánchez | 280 | 2 | |
 | Susaeta | 49 | 2 | |
 | Leonardo Ulloa | 32 | 2 | |
| 36 |  | Alexandre Alemão | 48 | 1 |
 | Amaya | 28 | 1 | |
 | Arteaga | 29 | 1 | |
 | Bebé | 187 | 1 | |
 | Calderón | 113 | 1 | |
 | Nery Castillo | 15 | 1 | |
 | Diego Torres | 5 | 1 | |
 | Nicolás Fedor | 46 | 1 | |
 | Jorge De Frutos | 161 | 1 | |
 | Juan Villar | 14 | 1 | |
 | Gaël Kakuta | 47 | 1 | |
 | Koke | 6 | 1 | |
 | Korino | 83 | 1 | |
 | Landáburu | 66 | 1 | |
 | Míchel | 36 | 1 | |
 | Randy Nteka | 120 | 1 | |
 | Yacine Qasmi | 60 | 1 | |
 | Andrei Ratiu | 110 | 1 | |
 | Raúl Tamudo | 37 | 1 | |
 | Rubén Castro | 41 | 1 | |
 | Sergi Guardiola | 57 | 1 |