All-time best penalty takers
| # | Name | Matches | 11m | |
|---|---|---|---|---|
| 1 |  | Joselu | 113 | 9 |
| 2 |  | Javi Moreno | 88 | 8 |
 | Lucas Pérez | 62 | 8 | |
| 4 |  | Viguera | 46 | 7 |
| 5 |  | Carlos Vicente | 82 | 5 |
 | Llorens | 81 | 5 | |
 | Pablo | 221 | 5 | |
| 8 |  | Lucas Boyé | 42 | 4 |
 | De Lucas | 132 | 4 | |
 | Kike García | 71 | 4 | |
 | Luis Rioja | 189 | 4 | |
 | Manu García | 268 | 4 | |
 | Nenê | 78 | 4 | |
| 14 |  | Aganzo | 30 | 3 |
 | Cosmin Contra | 80 | 3 | |
 | Joan Jordán | 27 | 3 | |
 | Julio Salinas | 52 | 3 | |
 | Salva Sevilla | 42 | 3 | |
| 19 |  | John Aloisi | 60 | 2 |
 | Arthur | 33 | 2 | |
 | Jonathan Calleri | 36 | 2 | |
 | Édgar Méndez | 118 | 2 | |
 | Meho Kodro | 31 | 2 | |
 | Rubén Navarro | 198 | 2 | |
 | Christian Santos | 39 | 2 | |
 | Toni Martínez | 84 | 2 | |
 | Villalibre | 38 | 2 | |
| 28 |  | Iván Alonso | 145 | 1 |
 | David Sánchez | 8 | 1 | |
 | Hermes Desio | 153 | 1 | |
 | Ranko Despotović | 26 | 1 | |
 | Edu Albácar | 28 | 1 | |
 | Euskalduna | 18 | 1 | |
 | Ibai | 92 | 1 | |
 | Adrian Ilie | 25 | 1 | |
 | Jandro | 64 | 1 | |
 | Jon Guridi | 148 | 1 | |
 | Juli | 76 | 1 | |
 | Kiko | 50 | 1 | |
 | Lecue | 36 | 1 | |
 | Manu Barreiro | 70 | 1 | |
 | Olivares | 14 | 1 | |
 | Raúl Sánchez | 27 | 1 | |
 | Rubén Sobrino | 71 | 1 | |
 | Téllez | 238 | 1 | |
 | Toni Moral | 92 | 1 |