All-time best penalty takers
| # | Name | Matches | 11m | |
|---|---|---|---|---|
| 1 |  | Ante Budimir | 231 | 24 |
 | Roberto Torres | 353 | 24 | |
| 3 |  | Javad Nekounam | 197 | 14 |
 | Puñal | 472 | 14 | |
| 5 |  | John Aloisi | 132 | 7 |
| 6 |  | Bustingorri | 328 | 5 |
 | Enrique Martín | 228 | 5 | |
 | Marañon | 90 | 5 | |
| 9 |  | Goikoetxea | 96 | 4 |
 | Muñoz | 172 | 4 | |
 | Jan Urban | 164 | 4 | |
 | Ziganda | 161 | 4 | |
| 13 |  | Aimar Oroz | 155 | 3 |
 | Chimy Ávila | 123 | 3 | |
 | Fran Mérida | 110 | 3 | |
 | Iriguibel | 104 | 3 | |
 | Iván Rosado | 153 | 3 | |
 | Martín Domínguez | 144 | 3 | |
 | Rubén García | 310 | 3 | |
 | Sola | 197 | 3 | |
 | Zamacona | 30 | 3 | |
| 22 |  | Àlex Fernández | 69 | 2 |
 | Fusté | 26 | 2 | |
 | Kike García | 79 | 2 | |
 | Raúl | 128 | 2 | |
 | Serena | 51 | 2 | |
| 27 |  | Adrián López | 46 | 1 |
 | Aguilá | 63 | 1 | |
 | Arozarena | 144 | 1 | |
 | Bayona | 139 | 1 | |
 | Brandon | 47 | 1 | |
 | David Timor | 47 | 1 | |
 | Enric Gallego | 40 | 1 | |
 | Gerardo | 10 | 1 | |
 | Iker Benito | 19 | 1 | |
 | Jonathan Dubasin | 13 | 1 | |
 | Juan Villar | 42 | 1 | |
 | Kike Barja | 242 | 1 | |
 | Kenan Kodro | 87 | 1 | |
 | Roman Kosecki | 34 | 1 | |
 | Pablo Orbaiz | 32 | 1 | |
 | Pepin | 257 | 1 | |
 | Recalde | 106 | 1 | |
 | Rípodas | 220 | 1 | |
 | Gerardo Rivero | 81 | 1 | |
 | Sabino | 50 | 1 | |
 | Sergio León | 36 | 1 | |
 | Jacek Ziober | 35 | 1 |