Additions
| from | Name | Pos | Team | Team | ||
|---|---|---|---|---|---|---|
| 06/2013 |  | Miroslav Đukić | MA |  | Real Valladolid | Valladolid |
| 01/2013 |  | Mario Arqués | MF |  | Valencia CF B | Valencia B |
| 12/2012 | | Ernesto Valverde | MA | |||
| 12/2012 | | Jon Aspiazu | AS-CO | |||
| 12/2012 | | Voro | MA | |||
| 12/2012 | | José Antonio Pozanco | AT-C | |||
| 11/2012 | | Dalmau | DF | | Valencia CF B | Valencia B |
| 11/2012 | | Álex Quintanilla | DF | | Valencia CF B | Valencia B |
| 11/2012 | | Salva Ruiz | DF | | Valencia CF B | Valencia B |
| 09/2012 | | Carlos Delgado | DF | | Valencia CF B | Valencia B |
| 09/2012 | | Gayà | MF | | Valencia CF B | Valencia B |
| 09/2012 | | Portu | MF | | Valencia CF B | Valencia B |
| 08/2012 |  | Aly Cissokho | DF |  | Olympique Lyonnais | Lyonnais |
| 08/2012 |  | Nelson Valdez | FW |  | Rubin Kazan | Kazan |
| 07/2012 |  | Fernando Gago | MF |  | Real Madrid | Real Madrid |
| 07/2012 | | Felipe | GK |  | RCD Mallorca B | Mallorca |
| 07/2012 |  | João Pereira | DF |  | Sporting CP | Sporting |
| 07/2012 |  | Andrés Guardado | MF |  | Deportivo A Coruña | Deportivo |
| 07/2012 | | Alejandro Domínguez | FW |  | River Plate | River Plate |
| 07/2012 | | Jonathan Viera | FW |  | UD Las Palmas | UD Las Palmas |
| 07/2012 | | Mauricio Pellegrino | MA | |||
| 07/2012 | | Carlos Compagnucci | AS-CO | |||
| 07/2012 | | Xavi Tamarit | AS-CO | |||
| 07/2012 | | Gabriel Macaya | AT-C |  | Banfield | Banfield |
Departures
| from | Name | Pos | Team | Team | ||
|---|---|---|---|---|---|---|
| 04/2013 | | Xavi Tamarit | AS-CO |  | Estudiantes | Estudiantes |
| 01/2013 | | Fernando Gago | MF |  | Vélez Sarsfield | Vélez Sársfield |
| 09/2012 | | Pablo Hernández | MF |  | Swansea City | Swansea |
| 09/2012 | | Paco Alcácer | FW |  | Getafe CF | Getafe |
| 08/2012 | | Alejandro Domínguez | FW |  | Rayo Vallecano | Rayo |
| 07/2012 | | Cristiano Figueiredo | GK |  | S.C. Braga | S.C. Braga |
| 07/2012 | | Bruno Saltor | DF |  | Brighton & Hove Albion | Brighton & Hove |
| 07/2012 | | Dealbert | DF |  | Kuban Krasnodar (1928-2018) | Kuban |
| 07/2012 | | Jordi Alba | DF |  | FC Barcelona | Barcelona |
| 07/2012 |  | Hedwiges Maduro | MF |  | Sevilla FC | Sevilla |
| 07/2012 |  | Mehmet Topal | MF |  | Fenerbahçe | Fenerbahçe |
| 07/2012 | | Aduriz | FW |  | Athletic Club | Athletic |
| 07/2012 | | Unai Emery | MA |  | Spartak Moskva | Spartak |
| 07/2012 | | Carcedo | AS-CO | | Spartak Moskva | Spartak |