All-time best penalty takers
| # | Name | Matches | 11m | |
|---|---|---|---|---|
| 1 |  | Roger Martí | 234 | 17 |
| 2 |  | José Morales | 377 | 12 |
| 3 |  | Rubén Suárez | 137 | 8 |
| 4 |  | Gabriel Amato | 39 | 7 |
 | Rivera | 118 | 7 | |
| 6 |  | Barkero | 75 | 6 |
 | José Campaña | 208 | 6 | |
| 8 |  | De la Fuente | 115 | 5 |
 | Ian Harte | 66 | 5 | |
 | Salillas | 78 | 5 | |
| 11 |  | Alberto Saavedra | 55 | 3 |
 | Barral | 74 | 3 | |
 | Gonzalo Melero | 94 | 3 | |
 | Míchel | 51 | 3 | |
 | Parri | 24 | 3 | |
| 16 |  | Enis Bardhi | 162 | 2 |
 | Nabil El Zhar | 114 | 2 | |
 | Iborra | 256 | 2 | |
 | Igor | 11 | 2 | |
 | Iván Romero | 102 | 2 | |
 | Joni Montiel | 47 | 2 | |
 | Riga Mustapha | 108 | 2 | |
 | Pepin | 42 | 2 | |
 | Serafín | 45 | 2 | |
| 25 |  | Felipe Caicedo | 29 | 1 |
 | Farinós | 30 | 1 | |
 | Guerrero | 2 | 1 | |
 | Andreas Ivanschitz | 51 | 1 | |
 | Jofre | 108 | 1 | |
 | Josemi | 25 | 1 | |
 | Juan Muñoz | 6 | 1 | |
 | Giorgi Kochorashvili | 66 | 1 | |
 | Lima | 68 | 1 | |
 | Ivi López | 32 | 1 | |
 | Predrag Mijatović | 21 | 1 | |
 | Pablo Martínez | 155 | 1 | |
 | Quini | 0 | 1 | |
 | Giuseppe Rossi | 17 | 1 | |
 | Salva | 14 | 1 | |
 | Samuel | 47 | 1 | |
 | Sergio León | 59 | 1 | |
 | Soldado | 51 | 1 | |
 | Cristhian Stuani | 33 | 1 | |
 | Verza | 52 | 1 | |
 | Viqueira | 10 | 1 | |
 | Wanderley | 44 | 1 | |
 | Xisco Muñoz | 55 | 1 |