All-time best penalty takers
| # | Name | Matches | 11m | |
|---|---|---|---|---|
| 1 |  | José Zalazar | 194 | 26 |
| 2 |  | Rubén Cruz | 112 | 11 |
| 3 |  | Higinio Marín | 107 | 9 |
| 4 |  | Calle | 77 | 7 |
| 5 |  | Barkero | 66 | 6 |
 | Antonio Pacheco | 88 | 6 | |
| 7 |  | Jefté Betancor | 43 | 5 |
 | Maikel Mesa | 55 | 5 | |
 | Cristhian Stuani | 39 | 5 | |
| 10 |  | Alberto Quiles | 67 | 4 |
 | Álvaro Jiménez | 64 | 4 | |
 | Jérémie Bela | 71 | 4 | |
 | Nenad Bjelica | 92 | 4 | |
 | Perera | 75 | 4 | |
 | Susaeta | 94 | 4 | |
 | Verza | 100 | 4 | |
| 17 |  | Dani Rodríguez | 80 | 3 |
 | Eugeni | 36 | 3 | |
 | Rey Manaj | 41 | 3 | |
 | Manu Fuster | 195 | 3 | |
 | Jonathan Mejía | 29 | 3 | |
 | Morcillo | 63 | 3 | |
 | Sala | 103 | 3 | |
 | Toril | 45 | 3 | |
| 25 |  | Aranda | 50 | 2 |
 | Diego Costa | 35 | 2 | |
 | Jandro | 21 | 2 | |
 | Kike | 20 | 2 | |
 | Parri | 116 | 2 | |
 | Samu Delgado | 98 | 2 | |
 | Tato | 37 | 2 | |
 | Nenad Vanić | 12 | 2 | |
 | Roman Zozulya | 142 | 2 | |
| 34 |  | Aketxe | 25 | 1 |
 | Alberto Abengózar | 4 | 1 | |
 | Alex Pérez | 22 | 1 | |
 | Basti | 105 | 1 | |
 | Bermejo | 32 | 1 | |
 | César Díaz | 137 | 1 | |
 | Chumbi | 36 | 1 | |
 | Edu García | 26 | 1 | |
 | Èric Montes | 30 | 1 | |
 | Garzón | 2 | 1 | |
 | Héctor Hernández | 57 | 1 | |
 | Iván Sánchez | 20 | 1 | |
 | José Fran | 37 | 1 | |
 | Melgar | 39 | 1 | |
 | Ortuño | 79 | 1 | |
 | Toché | 22 | 1 | |
 | Dragan Vulević | 25 | 1 |