All-time best penalty takers
| # | Name | Matches | 11m | |
|---|---|---|---|---|
| 1 |  | Juan Romero | 183 | 14 |
| 2 |  | Edu Albácar | 187 | 12 |
 | Nino | 452 | 12 | |
| 4 |  | Fidel | 235 | 11 |
 | Juan Voglino | 118 | 11 | |
| 6 |  | Moisés | 79 | 8 |
| 7 |  | Jorge Molina | 38 | 7 |
| 8 |  | Sergio León | 56 | 6 |
| 9 |  | Xavi Torres | 29 | 5 |
| 10 |  | Iborra | 303 | 4 |
 | Pere Milla | 146 | 4 | |
| 12 |  | André Silva | 32 | 3 |
 | Juan Cobo | 47 | 3 | |
 | Edu García | 34 | 3 | |
 | Lombán | 64 | 3 | |
 | Melenchón | 97 | 3 | |
| 17 |  | Ángel | 85 | 2 |
 | Nicolás Castro | 77 | 2 | |
 | César Rodríguez | 27 | 2 | |
 | David Fuster | 36 | 2 | |
 | Nicolás Fernández Mercau | 97 | 2 | |
 | Iván Sánchez | 119 | 2 | |
 | Lolo Plá | 24 | 2 | |
 | Mourad Daoudi | 81 | 2 | |
 | Peragón | 83 | 2 | |
 | Raúl Fuster | 84 | 2 | |
 | Marcelo Trobbiani | 65 | 2 | |
 | Vavá | 184 | 2 | |
| 29 |  | Mariano Armentano | 66 | 1 |
 | Benja | 66 | 1 | |
 | Lucas Boyé | 100 | 1 | |
 | Facundo Buonanotte | 9 | 1 | |
 | Carlos Castro | 13 | 1 | |
 | Gastón Casas | 29 | 1 | |
 | Claudio Barragán | 73 | 1 | |
 | Walter Coelho | 46 | 1 | |
 | Company | 17 | 1 | |
 | Curro | 80 | 1 | |
 | Fer Niño | 12 | 1 | |
 | Generelo | 110 | 1 | |
 | Guillot | 14 | 1 | |
 | Huegún | 19 | 1 | |
 | Iago | 13 | 1 | |
 | Ilie Sánchez | 28 | 1 | |
 | Jandro | 9 | 1 | |
 | Jonathas | 52 | 1 | |
 | José Vega | 32 | 1 | |
 | Juan Carlos | 7 | 1 | |
 | Sory Kaba | 90 | 1 | |
 | Linares | 48 | 1 | |
 | Julio Lorant | 21 | 1 | |
 | Manuel Sánchez | 99 | 1 | |
 | Javier Matilla | 15 | 1 | |
 | Meca | 62 | 1 | |
 | Melgar | 37 | 1 | |
 | Dagoberto Moll | 21 | 1 | |
 | Nacho Gil | 11 | 1 | |
 | Óscar Plano | 59 | 1 | |
 | Pedro | 30 | 1 | |
 | Yacine Qasmi | 42 | 1 | |
 | Rafa Mir | 29 | 1 | |
 | Héctor Ramos | 63 | 1 | |
 | Federico Redondo | 24 | 1 | |
 | Rodri | 36 | 1 | |
 | Dennis Șerban | 36 | 1 | |
 | Damián Suárez | 102 | 1 | |
 | Tete Morente | 166 | 1 |