All-time best penalty takers
| # | Name | Matches | 11m | |
|---|---|---|---|---|
| 1 |  | Álex | 308 | 21 |
| 2 |  | Airam Cabrera | 77 | 9 |
 | Manolo Pérez | 87 | 9 | |
| 4 |  | Jorge González | 152 | 7 |
 | Lucas Lobos | 65 | 7 | |
| 6 |  | Alcaraz | 112 | 6 |
| 7 |  | Ibáñez Conde | 33 | 4 |
 | Jonathan Mejía | 54 | 4 | |
 | Abraham Paz | 143 | 4 | |
| 10 |  | Jonathan Sesma | 164 | 3 |
 | José González | 96 | 3 | |
 | Montero | 108 | 3 | |
 | Oliva | 203 | 3 | |
| 14 |  | Álvaro Negredo | 105 | 2 |
 | José Mari | 166 | 2 | |
 | Parri | 22 | 2 | |
| 17 |  | Aitor García | 54 | 1 |
 | Antonio Cordero | 34 | 1 | |
 | Barral | 34 | 1 | |
 | Théo Bongonda | 32 | 1 | |
 | Borge | 1 | 1 | |
 | Carrillo | 49 | 1 | |
 | Chris Ramos | 92 | 1 | |
 | David Sánchez | 22 | 1 | |
 | Oscar Dertycia | 21 | 1 | |
 | Diego Tristán | 29 | 1 | |
 | Güiza | 52 | 1 | |
 | Juan Bezares | 126 | 1 | |
 | Lucas Pérez | 38 | 1 | |
 | Darwin Machís | 36 | 1 | |
 | Mané | 55 | 1 | |
 | Miguel Ángel | 17 | 1 | |
 | Miguel García | 45 | 1 | |
 | Ortuño | 42 | 1 | |
 | Iván Šaponjić | 9 | 1 | |
 | Iuri Tabatadze | 20 | 1 | |
 | Mariano Toedtli | 29 | 1 | |
 | Urko Izeta | 13 | 1 | |
 | Fabián Vázquez | 30 | 1 |