All-time best penalty takers
| # | Name | Matches | 11m | |
|---|---|---|---|---|
| 1 |  | Gerard Deulofeu | 36 | 5 |
| 2 |  | Iniesta | 13 | 3 |
 | Mikel Oyarzabal | 25 | 3 | |
 | Thiago | 21 | 3 | |
| 5 |  | Bustingorri | 5 | 2 |
 | Isco | 19 | 2 | |
 | Juan Mata | 19 | 2 | |
 | Óscar García | 21 | 2 | |
 | Sergio Gómez | 18 | 2 | |
| 10 |  | Julio Álvarez | 3 | 1 |
 | Álvaro Morata | 13 | 1 | |
 | Angulo | 13 | 1 | |
 | Bojan | 19 | 1 | |
 | Butragueño | 5 | 1 | |
 | Capel | 23 | 1 | |
 | Dani Olmo | 14 | 1 | |
 | Hierro | 5 | 1 | |
 | Hugo Duro | 1 | 1 | |
 | Iker Bravo | 10 | 1 | |
 | Javier Guerra | 21 | 1 | |
 | Juan Miranda | 24 | 1 | |
 | Julio Suárez | 3 | 1 | |
 | Kepa | 7 | 1 | |
 | Manzanedo | 2 | 1 | |
 | Mikel Arteta | 8 | 1 | |
 | Portillo | 5 | 1 | |
 | Robert | 17 | 1 | |
 | Roberto López | 3 | 1 | |
 | Roger | 10 | 1 | |
 | Sergio Canales | 10 | 1 | |
 | Xavi | 23 | 1 |