All-time best penalty takers
| # | Name | Matches | 11m | |
|---|---|---|---|---|
| 1 |  | Lanzarote | 93 | 8 |
| 2 |  | Telechea | 74 | 7 |
 | Aníbal Zurdo | 95 | 7 | |
| 4 |  | Perico Alonso | 67 | 5 |
| 5 |  | Edgar | 112 | 4 |
 | Felipe Sanchón | 56 | 4 | |
 | Gato | 115 | 4 | |
 | Jacobo | 35 | 4 | |
 | Rubén Martínez | 62 | 4 | |
 | Sergio Cortés | 50 | 4 | |
| 11 |  | Collantes | 106 | 3 |
 | Garzón | 75 | 3 | |
 | Rubio | 34 | 3 | |
| 14 |  | Antonio Hidalgo | 115 | 2 |
 | Coscia | 41 | 2 | |
 | Juvenal | 50 | 2 | |
 | Stoichkov | 38 | 2 | |
 | Torrent | 73 | 2 | |
 | Vidal | 64 | 2 | |
| 20 |  | Aarón Bueno | 28 | 1 |
 | Alberto | 28 | 1 | |
 | Álex Cortell | 14 | 1 | |
 | Arteaga | 51 | 1 | |
 | Barbarà | 43 | 1 | |
 | Borjas Martín | 16 | 1 | |
 | Kenneth Brylle | 8 | 1 | |
 | Clausí | 22 | 1 | |
 | De Diego | 26 | 1 | |
 | Dieste | 21 | 1 | |
 | Escudero | 40 | 1 | |
 | Héber | 41 | 1 | |
 | Vicente Jara | 17 | 1 | |
 | Moha Keita | 26 | 1 | |
 | Lino | 54 | 1 | |
 | Marc Fernández | 32 | 1 | |
 | Marcos Baselga | 25 | 1 | |
 | Ortuño | 62 | 1 | |
 | Palau | 117 | 1 | |
 | Pallas | 106 | 1 | |
 | Quiles | 55 | 1 | |
 | Ribes | 13 | 1 | |
 | Juan Seminario | 35 | 1 | |
 | Urri Orriols | 74 | 1 |