All-time best penalty takers
| # | Name | Matches | 11m | |
|---|---|---|---|---|
| 1 |  | Marc Martínez | 94 | 9 |
| 2 |  | Mate Bilić | 40 | 7 |
| 3 |  | Josemi | 45 | 6 |
| 4 |  | Chuli | 62 | 5 |
 | Pedro Martín | 36 | 5 | |
| 6 |  | Raúl González | 52 | 4 |
 | Rubio | 45 | 4 | |
| 8 |  | Raúl Fuster | 101 | 3 |
 | Salva Chamorro | 38 | 3 | |
| 10 |  | Cristian Gómez | 27 | 2 |
 | Diego Suárez | 39 | 2 | |
 | Nakor | 104 | 2 | |
 | Nierga | 58 | 2 | |
 | Quim Araùjo | 40 | 2 | |
 | Unai García | 33 | 2 | |
| 16 |  | Abel Molinero | 48 | 1 |
 | Adrià Gené | 34 | 1 | |
 | Arnal | 33 | 1 | |
 | Calderón | 41 | 1 | |
 | Christian Alfonso | 31 | 1 | |
 | Éder Díez | 24 | 1 | |
 | Virgilio Hernández | 43 | 1 | |
 | Iván Agudo | 21 | 1 | |
 | Jaime Mata | 46 | 1 | |
 | Jesús Imaz | 27 | 1 | |
 | Juanto Ortuño | 55 | 1 | |
 | Moha Keita | 29 | 1 | |
 | Manu Molina | 33 | 1 | |
 | Moreno | 42 | 1 | |
 | Mumo Muñoz | 27 | 1 | |
 | Nil | 2 | 1 | |
 | Pellicer | 19 | 1 | |
 | Ramón | 29 | 1 | |
 | Renaldo | 17 | 1 | |
 | Roa | 50 | 1 | |
 | Simeón | 52 | 1 | |
 | Telechea | 24 | 1 | |
 | José Valle | 18 | 1 | |
 | Xisco | 1 | 1 |