All-time best penalty takers
| # | Name | Matches | 11m | |
|---|---|---|---|---|
| 1 |  | Manu Sarabia | 82 | 5 |
| 2 |  | Abadía | 183 | 4 |
 | Toni Polster | 42 | 4 | |
| 4 |  | Marín | 63 | 3 |
 | Quique Setién | 122 | 3 | |
 | Oleg Salenko | 53 | 3 | |
| 7 |  | Manolo Pérez | 42 | 2 |
 | Amaro Nadal | 35 | 2 | |
| 9 |  | Antonio Alzamendi | 62 | 1 |
 | Ricardo Canals | 32 | 1 | |
 | Gilson | 37 | 1 | |
 | Herrero | 224 | 1 | |
 | Jorge Alonso | 47 | 1 | |
 | Dejan Marković | 102 | 1 | |
 | Quico Rey | 37 | 1 | |
 | Sánchez Lorenzo | 60 | 1 |