All-time best penalty takers
| # | Name | Matches | 11m | |
|---|---|---|---|---|
| 1 |  | Corpas | 207 | 13 |
| 2 |  | Charles | 100 | 9 |
| 3 |  | Aketxe | 94 | 6 |
 | Arruabarrena | 96 | 6 | |
 | Gorka Brit | 44 | 6 | |
| 6 |  | Adrián | 68 | 5 |
 | Fabián Orellana | 81 | 5 | |
 | Stoichkov | 126 | 5 | |
| 9 |  | Alaña | 111 | 4 |
 | Goiria | 37 | 4 | |
| 11 |  | Barkero | 41 | 3 |
 | Borja Bastón | 39 | 3 | |
 | Gaizka Garitano | 149 | 3 | |
 | Javi Martón | 55 | 3 | |
 | Quique | 118 | 3 | |
 | Saúl Berjón | 65 | 3 | |
| 17 |  | Esteban Burgos | 54 | 2 |
 | Edu Expósito | 117 | 2 | |
 | Llorente | 81 | 2 | |
 | Suances | 16 | 2 | |
| 21 |  | Azkoitia | 37 | 1 |
 | Cabrejo | 82 | 1 | |
 | César Caneda | 42 | 1 | |
 | Pablo de Blasis | 58 | 1 | |
 | Marko Dmitrović | 131 | 1 | |
 | Eneko Romo | 29 | 1 | |
 | Guerrero | 41 | 1 | |
 | Iván Gil | 22 | 1 | |
 | Joan Jordán | 75 | 1 | |
 | Jorge Sánchez | 74 | 1 | |
 | Nolaskoain | 124 | 1 | |
 | Pedro León | 119 | 1 | |
 | Federico Piovaccari | 30 | 1 | |
 | Recio | 20 | 1 | |
 | Saizar | 44 | 1 | |
 | Toni Villa | 28 | 1 | |
 | Txiki | 42 | 1 | |
 | Urraka | 11 | 1 | |
 | Yagüe | 59 | 1 |