Gameplan
| Date | Round | Match | Match | Res. | Attendance | |
|---|---|---|---|---|---|---|
| 12.09.1965 |  | Matchday 2 | RCD Espanyol - Zaragoza | RCD - SAR | 1:1 | |
| 26.09.1965 | | Matchday 4 | RCD Espanyol - Sevilla | RCD - SEV | 1:0 | |
| 10.10.1965 | | Matchday 6 | RCD Espanyol - Athletic | RCD - ATH | 3:4 | |
| 31.10.1965 | | Matchday 8 | RCD Espanyol - Barcelona | RCD - BAR | 1:1 | |
| 20.11.1965 | | Matchday 10 | RCD Espanyol - Sabadell | RCD - SAB | 2:1 | |
| 24.11.1965 |  | 2. Round 2nd leg | RCD Espanyol - Sporting | RCD - SPO | 4:3 | 30.000 |
| 15.12.1965 | | 2. Round Decider | RCD Espanyol - Sporting | RCD - SPO | 2:1 | 20.200 |